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• W4248889273 endingPage "8874" @default.
• W4248889273 startingPage "8870" @default.
• W4248889273 abstract "The complete reductive cleavage of the triple bond in carbon monoxide was achieved using a lithium disilenide at room temperature. The CC-coupled product can be regarded as a silanone dimer with pending alkyne and silirene moieties and incorporates two equivalents of CO per disilenide unit. A formation mechanism via ketenyl intermediates is proposed on the basis of DFT calculations and elucidated experimentally by employing Group 6 metal carbonyls as both stabilizing entity and source of CO in the reaction with disilenide. The isolation of cyclic silylene complexes with weakly donating ketenyl donor groups further supports the mechanistic scenario." @default.
• W4248889273 created "2022-05-12" @default.
• W4248889273 creator A5024569923 @default.
• W4248889273 creator A5028919411 @default.
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• W4248889273 creator A5072518846 @default.
• W4248889273 creator A5078937085 @default.
• W4248889273 creator A5083296313 @default.
• W4248889273 date "2015-06-18" @default.
• W4248889273 modified "2023-10-10" @default.
• W4248889273 title "Reductive Cleavage of Carbon Monoxide by a Disilenide" @default.
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