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- W4248889670 abstract "The hydrolysis of (CH3)2Sn2+ was studied potentiometrically, in different aqueous media (sodium and tetramethylammonium chlorides, sodium nitrate, sodium perchlorate, and sodium sulfate), in a wide range of ionic strength, at t = 25 °C. Least squares calculations are consistent with the formation of the species [M(OH)]+, [M(OH)2]0, [M(OH)3]-, [M2(OH)2]2+, and [M2(OH)3]+, with M = (CH3)2Sn2+. The dependence on ionic strength for different salt solutions was taken into account by using a Debye−Hückel type equation. Medium effects were explained by considering the formation of the chloride and sulfate complexes, [(CH3)2SnCl]+, [(CH3)2SnCl2]0, [(CH3)2Sn(OH)Cl]0, [(CH3)2Sn(OH)2Cl]-, [(CH3)2Sn(SO4)]0, [(CH3)2Sn(SO4)2]2-, [(CH3)2Sn(OH)(SO4)]-, and [(CH3)2Sn(OH)2(SO4)]2-. Thermodynamic hydrolysis constants of (CH3)2Sn2+ and formation constants of the complex species with chloride and sulfate ions are reported." @default.
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- W4248889670 date "1996-01-01" @default.
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- W4248889670 title "Hydrolysis of (CH<sub>3</sub>)<sub>2</sub>Sn<sup>2+</sup> in Different Ionic Media: Salt Effects and Complex Formation" @default.
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- W4248889670 doi "https://doi.org/10.1021/je9502915" @default.
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