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- W4248936255 abstract "In previous work, steady-state isotope switching was conducted on Pt/ceria with H2O and D2O, and a normal kinetic isotope effect was observed. Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) indicated that the surface coverage of H-formate was more limited by the WGS rate than that of D-formate, linking the rate limiting step to the breaking of the formate C–H bond. In this work, the transient response of the decomposition of H and D formates was followed thermally and in the presence of H2O and D2O. A normal kinetic isotope effect was again obtained, in agreement with our previous findings, and those reported by Shido and Iwasawa. Consistent with their work, water was found to assist in promoting the forward decomposition of surface formates to hydrogen and unidentate carbonate, the precursor to CO2." @default.
- W4248936255 created "2022-05-12" @default.
- W4248936255 creator A5071565771 @default.
- W4248936255 date "2004-05-01" @default.
- W4248936255 modified "2023-09-25" @default.
- W4248936255 title "Low temperature water-gas shift: kinetic isotope effect observed for decomposition of surface formates for Pt/ceria catalysts" @default.
- W4248936255 doi "https://doi.org/10.1016/s0926-860x(04)00270-4" @default.
- W4248936255 hasPublicationYear "2004" @default.
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