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- W4249148975 abstract "Polymerer Cyanwasserstoff, üblicherweise als polymere Blausäure oder Azulminsäure bezeichnet, entsteht durch anionische Polymerisation von HCN in wäßriger Lösung. Die Reaktion verläuft über dimere Blausäure (Iminoacetonitril). Gleichzeitig findet zwischen γ-ständigen Nitril-Gruppen Ringschluß statt, wodurch das kettenförmige Polymer stabilisiert wird. Die Bruttozusammensetzung der polymeren Blausäure weicht von der Formel (HCN)x durch einen mehr oder minder großen Sauerstoff-Gehalt ab. Der Sauerstoff stammt aus Reaktionen mit dem Lösungsmittel. Die Beobachtung, daß polymere Blausäure Metallsalze, insbesondere Edelmetallsalze, in hoher Konzentration reversibel anzulagern vermag, macht sie zu einer technisch interessanten Verbindung." @default.
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- W4249148975 date "1960-06-07" @default.
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- W4249148975 title "Polymere Blausäure" @default.
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- W4249148975 doi "https://doi.org/10.1002/ange.19600721104" @default.
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