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- W4249231563 abstract "Abstract Here we provide evidence that the formation of PuO 2 nanoparticles from oxidized Pu VI under alkaline conditions proceeds through the formation of an intermediate Pu V solid phase, similar to NH 4 PuO 2 CO 3 , which is stable over a period of several months. For the first time, state‐of‐the‐art experiments at Pu M 4 and at L 3 absorption edges combined with theoretical calculations unambiguously allow to determine the oxidation state and the local structure of this intermediate phase." @default.
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- W4249231563 date "2019-11-06" @default.
- W4249231563 modified "2023-09-27" @default.
- W4249231563 title "A Novel Metastable Pentavalent Plutonium Solid Phase on the Pathway from Aqueous Plutonium(VI) to PuO <sub>2</sub> Nanoparticles" @default.
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- W4249231563 doi "https://doi.org/10.1002/ange.201911637" @default.
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