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- W4249280726 abstract "Abstract A palladium‐catalyzed C(sp 3 )−C(sp 2 ) Suzuki–Miyaura cross‐coupling of aryl boronic acids and α‐(trifluoromethyl)benzyl tosylates is reported. A readily available, air‐stable palladium catalyst was employed to access a wide range of functionalized 1,1‐diaryl‐2,2,2‐trifluoroethanes. Enantioenriched α‐(trifluoromethyl)benzyl tosylates were found to undergo cross‐coupling to give the corresponding enantioenriched cross‐coupled products with an overall inversion in configuration. The crucial role of the CF 3 group in promoting this transformation is demonstrated by comparison with non‐fluorinated derivatives." @default.
- W4249280726 created "2022-05-12" @default.
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- W4249280726 date "2017-08-15" @default.
- W4249280726 modified "2023-10-16" @default.
- W4249280726 title "Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of Secondary α-(Trifluoromethyl)benzyl Tosylates" @default.
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- W4249280726 doi "https://doi.org/10.1002/ange.201706631" @default.
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