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- W4249370822 abstract "Type III GR-S latex was found to be Newtonian at concentrations below a volume fraction of φ = 0.25 rubber. Between φ = 0.25 and φ = 0.47, the latex was Newtonian at low shearing rates, but non-Newtonian at higher ones. Above φ = 0.47, the flow was non-Newtonian at all rates of shear. Up to φ = 0.40, a single exponential flow equation covered the entire range of shearing stresses employed. Above the latter concentration, however, separate exponential flow equations had to be used for the low- and high-stress ranges. The flow constants N and η′ varied regularly with concentration, but in a manner more complex than observed with type V latex. The extension of the Einstein equation used before, namely, log (η′η0) = bZ where Z = αφ1 — αφ′, was again found to hold well from 0 to 0.60 volume fraction of rubber. Application of this equation to the low concentration region gave a proportionality constant between η′ and φ not far different from the Einstein 2.5. Again, extrapolation of the equation to infinite viscosity gave a volume fraction of rubber plus adsorbed soap monolayer equal to 0.73–0.74, a value very close to that expected for close packing of spheres." @default.
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- W4249370822 date "1953-02-01" @default.
- W4249370822 modified "2023-09-26" @default.
- W4249370822 title "Rheology of synthetic latex. III. concentration dependence of flow in type III GR-S latex" @default.
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- W4249370822 doi "https://doi.org/10.1016/0095-8522(53)90013-0" @default.
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