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• W4249383783 abstract "The sequential bond energies of Ti(CO)+ x, x = 1–7, are determined by collision induced dissociation with xenon in a guided ion beam tandem mass spectrometer. Values (in eV) for the (CO)x-1 Ti+—CO bond energies at 0 K are found to be 1⋅22 ± 0⋅006, 1⋅17 ± 0⋅04, 1⋅04 ± 0⋅04, 0⋅90 ± 0⋅05, 0.72 ± 0⋅04, 0⋅77 ± 0⋅03 and 0⋅54 ± 0⋅07 for x = 1–7, respectively. Although the bond energy of the Ti(CO)+ 7 17-electron complex is weak, it is stronger than would be expected for a ligand in the second ligand shell. The trends in the sequential bondenergies are discussed in terms of spin conservation and ligand field theory and are compared with the corresponding variations in the V(CO)+ x and Cr(CO)+ x systems." @default.
• W4249383783 created "2022-05-12" @default.
• W4249383783 creator A5012244806 @default.
• W4249383783 date "1996-05-01" @default.
• W4249383783 modified "2023-10-12" @default.
• W4249383783 title "Sequential bond energies of Ti(CO)+x,x= 1-7" @default.
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• W4249383783 doi "https://doi.org/10.1080/00268979650026686" @default.
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