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- W4249389076 abstract "[14644-71-4] AlClH2 (MW 64.45) InChI = 1S/Al.ClH.2H/h;1H;;/q+1;;;/p-1 InChIKey = SOGXWMAAMKKQCB-UHFFFAOYSA-M (reducing agent for a variety of functional groups1) Alternate Name: aluminum chloride hydride. Physical Data: the reagent is generated and used in situ. See Aluminum Chloride and Lithium Aluminum Hydride. Solubility: sol ether. Preparative Methods: (a) A solution of 0.57 g (15 mmol) of LiAlH4 in 15 mL of dry ether is mixed with a solution of 1.99 g (15 mmol) of AlCl3 in 15 mL of dry ether at −5 °C. The resulting mixed hydride solution is stirred at room temperature for 15 min.2 (b) To a precooled (0–5 °C) 20 mL of ether are added ground AlCl3 (400 mg, 3.00 mmol) and LiAlH4 (114 mg, 3.00 mmol), and the suspension is heated under reflux for 30 min.3 This procedure provides AlH2Cl as a suspension in ether. Analysis of Reagent Purity: Metal Hydrides Technical Bulletin No. 401 describes an apparatus and methodology for assay by means of hydrogen evolution. See also Rickborn and Quartucci.4 The IR spectrum of AlH2Cl shows a strong AlH stretching absorption band at 1852 cm−1.5 Handling, Storage, and Precautions: solutions or suspensions of AlH2Cl in ether are highly flammable and must be stored in the absence of moisture. Tetrahydrofuran is cleaved by AlH2Cl to yield the corresponding aluminum alkoxide and is thus not a suitable solvent." @default.
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- W4249389076 date "2001-04-15" @default.
- W4249389076 modified "2023-09-30" @default.
- W4249389076 title "Monochloroalane" @default.
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- W4249389076 doi "https://doi.org/10.1002/047084289x.rm284" @default.
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