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• W4249412526 endingPage "2500" @default.
• W4249412526 startingPage "2496" @default.
• W4249412526 abstract "Abstract The enantioselective synthesis of a series of C 2 ‐symmetric 3,3′‐diarylated 1,1′‐spirobiindane‐7,7′‐diols (3,3′‐diaryl‐SPINOLs) was developed by sequential Rh‐catalyzed twofold asymmetric conjugate arylation/BF 3 ‐promoted diastereoselective spirocyclization (>20:1 d.r. and >99 % ee for all examples). Some phosphoramidite ligands were prepared from the 3,3′‐Ph‐SPINOL and applied to several catalytic asymmetric reactions, and the 3,3′‐diarylated ligands showed higher enantioselectivities than the privileged nonsubstituted ligands." @default.
• W4249412526 created "2022-05-12" @default.
• W4249412526 creator A5001880581 @default.
• W4249412526 creator A5006564007 @default.
• W4249412526 creator A5022558345 @default.
• W4249412526 creator A5027182487 @default.
• W4249412526 creator A5029875635 @default.
• W4249412526 creator A5076027701 @default.
• W4249412526 creator A5084388409 @default.
• W4249412526 date "2019-01-21" @default.
• W4249412526 modified "2023-09-30" @default.
• W4249412526 title "Enantioselective Synthesis of 3,3′-Diaryl-SPINOLs: Rhodium-Catalyzed Asymmetric Arylation/BF₃ -Promoted Spirocyclization Sequence" @default.
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