Matches in SemOpenAlex for { <https://semopenalex.org/work/W4249416404> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W4249416404 abstract "<p>An SN2 mechanism was proposed for highly stereoselective glycosylation of benzoic acid with unprotected α-D-glucose under Mitsunobu conditions in dioxane, while an SN1 mechanism seems to be responsible for non-stereoselective glycosylation in DMF. The SN2-type glycosylation can be applicable to various unprotected pyranoses as glycosyl donors and a wide range of carboxylic acids, phenols, and imides as glycosyl acceptors, retaining its high stereoselectivity (34 examples). Glycosylation of a carboxylic acid with unprotected α-D-mannose proceeded also in an SN2 manner to directly afford a usually less accessible 1,2-<i>cis</i>-mannoside. An extremely short-step total synthesis of a middle molecule (1874 Da) natural glycoside with antitumor activity, coriariin A, was achieved via a double SN2 glycosylation strategy with two molecules of unprotected α-D-glucose.</p>" @default.
- W4249416404 created "2022-05-12" @default.
- W4249416404 creator A5005479552 @default.
- W4249416404 creator A5019265195 @default.
- W4249416404 creator A5020535149 @default.
- W4249416404 creator A5032771751 @default.
- W4249416404 creator A5055873487 @default.
- W4249416404 creator A5059137989 @default.
- W4249416404 creator A5060254895 @default.
- W4249416404 creator A5065590546 @default.
- W4249416404 creator A5079615736 @default.
- W4249416404 creator A5089902442 @default.
- W4249416404 date "2019-12-03" @default.
- W4249416404 modified "2023-09-29" @default.
- W4249416404 title "SN2-Type Glycosylation with Unprotected Pyranoses" @default.
- W4249416404 doi "https://doi.org/10.26434/chemrxiv.11276384" @default.
- W4249416404 hasPublicationYear "2019" @default.
- W4249416404 type Work @default.
- W4249416404 citedByCount "0" @default.
- W4249416404 crossrefType "posted-content" @default.
- W4249416404 hasAuthorship W4249416404A5005479552 @default.
- W4249416404 hasAuthorship W4249416404A5019265195 @default.
- W4249416404 hasAuthorship W4249416404A5020535149 @default.
- W4249416404 hasAuthorship W4249416404A5032771751 @default.
- W4249416404 hasAuthorship W4249416404A5055873487 @default.
- W4249416404 hasAuthorship W4249416404A5059137989 @default.
- W4249416404 hasAuthorship W4249416404A5060254895 @default.
- W4249416404 hasAuthorship W4249416404A5065590546 @default.
- W4249416404 hasAuthorship W4249416404A5079615736 @default.
- W4249416404 hasAuthorship W4249416404A5089902442 @default.
- W4249416404 hasConcept C161790260 @default.
- W4249416404 hasConcept C178790620 @default.
- W4249416404 hasConcept C181647583 @default.
- W4249416404 hasConcept C185592680 @default.
- W4249416404 hasConcept C2775887612 @default.
- W4249416404 hasConcept C2777313579 @default.
- W4249416404 hasConcept C2780906977 @default.
- W4249416404 hasConcept C55493867 @default.
- W4249416404 hasConcept C71240020 @default.
- W4249416404 hasConcept C96765332 @default.
- W4249416404 hasConceptScore W4249416404C161790260 @default.
- W4249416404 hasConceptScore W4249416404C178790620 @default.
- W4249416404 hasConceptScore W4249416404C181647583 @default.
- W4249416404 hasConceptScore W4249416404C185592680 @default.
- W4249416404 hasConceptScore W4249416404C2775887612 @default.
- W4249416404 hasConceptScore W4249416404C2777313579 @default.
- W4249416404 hasConceptScore W4249416404C2780906977 @default.
- W4249416404 hasConceptScore W4249416404C55493867 @default.
- W4249416404 hasConceptScore W4249416404C71240020 @default.
- W4249416404 hasConceptScore W4249416404C96765332 @default.
- W4249416404 hasLocation W42494164041 @default.
- W4249416404 hasOpenAccess W4249416404 @default.
- W4249416404 hasPrimaryLocation W42494164041 @default.
- W4249416404 hasRelatedWork W10009036 @default.
- W4249416404 hasRelatedWork W16105460 @default.
- W4249416404 hasRelatedWork W19717034 @default.
- W4249416404 hasRelatedWork W24691256 @default.
- W4249416404 hasRelatedWork W26917244 @default.
- W4249416404 hasRelatedWork W27250091 @default.
- W4249416404 hasRelatedWork W32015012 @default.
- W4249416404 hasRelatedWork W7917182 @default.
- W4249416404 hasRelatedWork W931953 @default.
- W4249416404 hasRelatedWork W9858395 @default.
- W4249416404 isParatext "false" @default.
- W4249416404 isRetracted "false" @default.
- W4249416404 workType "article" @default.