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- W4249455560 abstract "Employing 1-(2-Aminoethyl) piperazine as a template, a new organically templated layered zinc phosphate–phosphite (C6H17N3)[Zn4(PO4)2(HPO3)2] has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group Cc with a=5.3272(11) Å, b=17.146(3) Å, c=22.071(4) Å, β=94.58(3)°, V=2009.5(7) Å3, Z=4, R1=0.0201 (I>2σ(I)) and wR2=0.0812 (all data). The inorganic network is based on strictly alternating ZnO4 tetrahedral units and P-centered units including PO4 tetrahedra and HPO3 pseudo-pyramids forming a double layered structure that contains columns of double six-membered rings. The diprotonated 1-(2-Aminoethyl) piperazine molecules reside in the interlayer region and interact with the inorganic network through H-bonds." @default.
- W4249455560 created "2022-05-12" @default.
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- W4249455560 date "2004-05-01" @default.
- W4249455560 modified "2023-09-25" @default.
- W4249455560 title "(C6H17N3)6Zn4(PO4)2(HPO3)29: a new layered zinc phosphate?phosphite templated by 1-(2-Aminoethyl) piperazine*1" @default.
- W4249455560 doi "https://doi.org/10.1016/s0022-4596(04)00145-8" @default.
- W4249455560 hasPublicationYear "2004" @default.
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