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- W4249569183 abstract "The breakaway oxidation, mainly at 850°C, of 2.5% tin-zirconium alloy in oxygen has been investigated by thermogravimetric measurements, electron microscopic observations, electron-probe microanalysis and X-ray diffraction studies. On the post-breakaway stage, the oxidation kinetics was largely dependent on the pressure of oxygen, and the significant cracking of the oxide film was observed. The electron-probe microanalysis and X-ray diffraction studies indicated that the tin in the alloy was precipitated as the intermetallic compound of ZrSn at the oxide/metal interface, and suggested that the oxide film has a multilayer structure consisting of ZrO2 and (ZrSn)O2 layers. The mechanism of the heavy breakaway phenomena of tin-zirconium alloy at high temperature was discussed on the basis of the behavior of tin in the alloy, and it was concluded that stress betweeh the layers of ZrO2 and (ZrSn)O2 induced the cracks of the oxide film and permitted the increased oxidation." @default.
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- W4249569183 date "1966-01-01" @default.
- W4249569183 modified "2023-09-30" @default.
- W4249569183 title "High-Temperature Oxidation Mechanism on 2.5% Tin-Zirconium Alloy" @default.
- W4249569183 doi "https://doi.org/10.2320/jinstmet1952.30.3_270" @default.
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