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- W4249606472 abstract "Abstract In targeting reduced valent lanthanide chalcogenides, we report the first nanoparticle synthesis of the mixed‐valent ferromagnets Eu 3 S 4 and EuSm 2 S 4 . Using divalent lanthanide halides with bis(trimethylsilyl)sulfide and oleylamine, we prepared nanoparticles of EuS, Eu 3 S 4 , EuSm 2 S 4 , SmS 1.9 , and Sm 3 S 4 . All nanoparticle phases were identified using powder X‐ray diffraction, transmission electron microscopy was used to confirm morphology and nanoparticle size, and magnetic susceptibility measurements for determining the ordering temperatures and valence. The UV/Vis, Raman and X‐ray photoelectron spectroscopies for each phase were compared. Surprisingly, the phase is influenced by the halide and the reaction temperature, where EuCl 2 formed EuS while EuI 2 formed Eu 3 S 4 , highlighting the role of kinetics in phase stabilization. Interestingly, at lower temperatures EuI 2 initially forms EuS, and converts over time to Eu 3 S 4 ." @default.
- W4249606472 created "2022-05-12" @default.
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- W4249606472 date "2021-09-17" @default.
- W4249606472 modified "2023-10-12" @default.
- W4249606472 title "Synthesis of Mixed‐Valent Lanthanide Sulfide Nanoparticles" @default.
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- W4249606472 doi "https://doi.org/10.1002/ange.202108993" @default.
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