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• W4249666583 abstract "[3153-26-2] C10H14O5V (MW 265.18) InChI = 1S/2C5H8O2.O.V/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;;/q;;;+2/p-2/b2*4-3-;; InChIKey = JFHJZWAQYMGNBE-SUKNRPLKSA-L (precatalyst for oxidation of several functional groups in combination with alkyl hydroperoxides or oxygen;1 especially useful for the regio- and diastereoselective epoxidation of allylic alcohols,2 the oxidation of tertiary amines to N-oxides,3 and the oxidation of sulfides to sulfoxides4 using an alkyl hydroperoxide as the oxidant) Alternative Name: bis(acetylacetonato)oxovanadium(IV). Physical Data: mp 235 °C (dec); d 1.50 g cm−3. Solubility: insol H2O; sol EtOH, CH2Cl2, CHCl3, C6H6. this reagent can be used in CH2Cl2, CHCl3, C6H6, toluene, DMF, EtOH, and CH3CN. Form Supplied in: blue-green crystals; widely available. Handling, Storage, and Precautions: generally used without further purification. Can be handled safely in the open. Should be stored in a cool, dry place in the absence of light. Contact with skin, eyes, and mucous membranes should be avoided. Toxic if swallowed. Generally performs best as an oxidation catalyst when used under anhydrous conditions. Oxidants contaminated with H2O such as 70% t-butyl hydroperoxide (TBHP) are therefore usually dried prior to use with VO(acac)2." @default.
• W4249666583 created "2022-05-12" @default.
• W4249666583 creator A5004362682 @default.
• W4249666583 creator A5022255445 @default.
• W4249666583 creator A5025662974 @default.
• W4249666583 creator A5070347979 @default.
• W4249666583 creator A5080543112 @default.
• W4249666583 date "2012-09-14" @default.
• W4249666583 modified "2023-09-30" @default.
• W4249666583 title "Vanadyl Bis(acetylacetonate)" @default.
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