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- W4249677963 abstract "The faradaic impedance technique is used to study the Ag/AgI,Ag+ electrode interphase. The interphase is described by a parallel connection of Warburg impedance, adsorption impedance and high-frequency double-layer capacitance. Consequently, the whole Ag/AgI electrode process is described by the faradaic parameter σ and three double-layer parameters: CHF, (CLF-CHF) and u′. These parameters are discussed particularly with regard to their dependence on the concentration of Ag+ ions in 0.01 mol dm−3 KNO3 supporting electrolyte. The conclusions are combined with those derived from analysis of the Ag/AgI,I− impedance data. Unlike the parameter σ which is mainly determined by the bulk concentration of either I− or Ag+ ions, the adsorption parameters (CLF-CHF) and u′ are in close relation with specific adsorption of I− ions in the whole pI and pAg range investigated. The possible influence of surface roughness on the Warburg impedance is evaluated. It is shown that surface roughness may explain the observed deviations of complex capacitance dispersion." @default.
- W4249677963 created "2022-05-12" @default.
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- W4249677963 date "1983-05-25" @default.
- W4249677963 modified "2023-09-23" @default.
- W4249677963 title "Analysis of the Ag/AgI electrode impedance" @default.
- W4249677963 doi "https://doi.org/10.1016/0368-1874(83)80167-1" @default.
- W4249677963 hasPublicationYear "1983" @default.
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