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- W4249683313 abstract "Researchers in Korea have developed a silver-loaded zinc oxide nanostructure that can significantly more reduce the operating temperature of acetylene gas sensors. This could mean cheaper, more efficient and more reliable sensors to ensure safety in the handling of this commonly used and highly unstable industrial gas. As well as being used in welding, acetylene is used as a raw material in the production of many products, including acetaldehyde, synthetic rubber, paints, fabrics, floor coverings, dry-cleaning solvents and insecticides. Acetylene is colourless and highly flammable, making it potentially very dangerous, especially as it is used in industrial settings where possible ignition sources can be plentiful. It is a particularly unstable substance when liquefied, pressurised, heated or mixed with air; all of which can also be expected in industrial use. With flame temperatures exceeding 3300°C, it is critical to avoid unexpected ignition of acetylene, and that requires the ability to sense tiny amounts. Numerous sensor approaches have been tried, but they usually operate at high temperatures (over 300°C). This incurs high power consumption and compromises their long-term stability. Their application has also been limited by issues including low sensitivity, poor selectivity and complex sensing material synthesis. In their Electronics Letters paper, the team from the University of Ulsan, South Korea, propose a nanostructure as the basis for efficient low-temperature acetylene sensors. The silver-loaded hierarchical zinc oxide nanostructure sensing material is synthesised uniformly through simple and rapid hydrothermal and photochemical processes. According to the team, the main challenges in this work were controlling the shape of the ZnO nanostructures and the size of the silver nanoparticles. They found that the pH level and working pressure were critical to shaping the ZnO nanostructure and that reaction time under UV light and operating power controlled the nucleation and growth of silver nanoparticles. The material produced has large specific surface area and numerous pores of the hierarchical ZnO nanostructure, and this, combined with the specific catalytic property of silver nanoparticles, is key to the success of the work. “It has high selectivity and long-term stability properties. Along with fast response, our fabricated sensor also exhibits excellent reproducibility, which is very important for the development of high performance practical sensors,” said Ulsan team member, Iftekhar Uddin. The sensor produced is highly selective for acetylene. For comparison, the team measured the responses of zinc oxide structures not loaded with silver to a range of gases (C2H2, H2, CO, CO2 and NO2) and found that the structures were most sensitive to hydrogen. The silver loaded structures, on the other hand, show negligible response to all these gases, apart from acetylene (C2H2). The current version of the sensor has an optimum operating temperature of 200°C, 100°C lower than the previous nanostructure-based approaches using zinc oxide loaded with other chemicals (Pt, Pd, Sm2O3, Ni). Although this is a significant improvement, the Ulsan team are working to get the optimum operating temperature down to 50-100°C. As part of this, they are now focusing on graphene nanosheets to support the silver loaded hierarchical zinc oxide nanostructure. It has been shown previously that embedding this kind of sensor in graphene helps to reduce working temperature." @default.
- W4249683313 created "2022-05-12" @default.
- W4249683313 date "2015-04-01" @default.
- W4249683313 modified "2023-09-27" @default.
- W4249683313 title "silver linings" @default.
- W4249683313 doi "https://doi.org/10.1049/el.2015.0836" @default.
- W4249683313 hasPublicationYear "2015" @default.
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