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• W4249700382 abstract "Mit 1,1,3,3-Tetramethyldisiloxan (TMDS) als Reduktionsmittel und [Fe(CO)5] oder [Fe3(CO)12] als Katalysator werden tertiäre Carboxamide in die entsprechenden Amine überführt. Die Reaktion lässt sich thermisch oder photochemisch durchführen. Anders als bei der Hydrosilanreduktion von Amiden mit Platin- oder Rutheniumkatalysatoren reduziert TMDS selbst in Gegenwart konkurrierender Amide bevorzugt Nitrogruppen." @default.
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• W4249700382 date "2009-11-10" @default.
• W4249700382 modified "2023-10-16" @default.
• W4249700382 title "Hydrosilane Reduction of Tertiary Carboxamides by Iron Carbonyl Catalysts" @default.
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• W4249700382 doi "https://doi.org/10.1002/ange.200905025" @default.
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