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- W4249969208 abstract "The synthesis of a unique class of polymers with a phosphorus-nitrogen backbone is described, focusing on poly-(dichlorophosphazene) and poly(organophosphazene) elastomers. Melt and solution polymerization techniques will be illustrated while briefly indicating the role of catalysts which give significantly improved rates of conversion and reproducibility in polymer properties. The elucidation of chain structure, molecular weight and polymer yield by various dilute solution techniques will be considered. Poly(dichlorophosphazene) is the common, though hydrolytically sensitive, precursor of a large number of poly(organophosphazene) polymers. Examples of technologically significant elastomers are shown which are obtained through the use of selected side group substituents attached to the phosphorus-nitrogen backbone. This article concludes with a brief mention of alternate synthetic methods which may lead to useful phosphazene polymers." @default.
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- W4249969208 date "1984-08-29" @default.
- W4249969208 modified "2023-10-14" @default.
- W4249969208 title "Phosphazene Elastomers" @default.
- W4249969208 doi "https://doi.org/10.1021/bk-1984-0260.ch009" @default.
- W4249969208 hasPublicationYear "1984" @default.
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