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- W4249982528 endingPage "17090" @default.
- W4249982528 startingPage "17081" @default.
- W4249982528 abstract "Abstract The utilizations of omnipresent, thermodynamically stable amides and aliphatic C(sp 3 )−H bonds for various functionalizations are ongoing challenges in catalysis. In particular, the direct coupling between the two functional groups has not been realized. Here, we report the synergistic activation of the two challenging bonds, the amide C−N and unactivated aliphatic C(sp 3 )−H, via metallaphotoredox catalysis to directly acylate aliphatic C−H bonds utilizing amides as stable and readily accessible acyl surrogates. N‐acylsuccinimides served as efficient acyl reagents for the streamlined synthesis of synthetically useful ketones from simple C(sp 3 )−H substrates. Detailed mechanistic investigations using both computational and experimental mechanistic studies were performed to construct a detailed and complete catalytic cycle. The origin of the superior reactivity of the N‐acylsuccinimides over other more reactive acyl sources such as acyl chlorides was found to be an uncommon reaction pathway which commences with C−H activation prior to oxidative addition of the acyl substrate." @default.
- W4249982528 created "2022-05-12" @default.
- W4249982528 creator A5030203661 @default.
- W4249982528 creator A5032254414 @default.
- W4249982528 creator A5034352898 @default.
- W4249982528 creator A5067358423 @default.
- W4249982528 creator A5085857842 @default.
- W4249982528 date "2020-07-29" @default.
- W4249982528 modified "2023-10-12" @default.
- W4249982528 title "Synergistic Activation of Amides and Hydrocarbons for Direct C(sp<sup>3</sup>)–H Acylation Enabled by Metallaphotoredox Catalysis" @default.
- W4249982528 cites W1929109117 @default.
- W4249982528 cites W1966430867 @default.
- W4249982528 cites W1979259658 @default.
- W4249982528 cites W1985511422 @default.
- W4249982528 cites W1996941025 @default.
- W4249982528 cites W2006180951 @default.
- W4249982528 cites W2007359483 @default.
- W4249982528 cites W2023271753 @default.
- W4249982528 cites W2037923207 @default.
- W4249982528 cites W2050956871 @default.
- W4249982528 cites W2066451204 @default.
- W4249982528 cites W2069006374 @default.
- W4249982528 cites W2076511248 @default.
- W4249982528 cites W2092157292 @default.
- W4249982528 cites W2123365931 @default.
- W4249982528 cites W2127983660 @default.
- W4249982528 cites W2146183505 @default.
- W4249982528 cites W2237104335 @default.
- W4249982528 cites W2273976432 @default.
- W4249982528 cites W2278700534 @default.
- W4249982528 cites W2284171265 @default.
- W4249982528 cites W2291222680 @default.
- W4249982528 cites W2338458965 @default.
- W4249982528 cites W2341379833 @default.
- W4249982528 cites W2342772717 @default.
- W4249982528 cites W2418356847 @default.
- W4249982528 cites W2430264813 @default.
- W4249982528 cites W2466522572 @default.
- W4249982528 cites W2499867668 @default.
- W4249982528 cites W2521387182 @default.
- W4249982528 cites W2521754066 @default.
- W4249982528 cites W2548072374 @default.
- W4249982528 cites W2549417026 @default.
- W4249982528 cites W2559934293 @default.
- W4249982528 cites W2573704736 @default.
- W4249982528 cites W2592989676 @default.
- W4249982528 cites W2599793474 @default.
- W4249982528 cites W2603073582 @default.
- W4249982528 cites W2608233938 @default.
- W4249982528 cites W2611482214 @default.
- W4249982528 cites W2620134880 @default.
- W4249982528 cites W2621292383 @default.
- W4249982528 cites W2667976850 @default.
- W4249982528 cites W2732218143 @default.
- W4249982528 cites W2732615433 @default.
- W4249982528 cites W2735651217 @default.
- W4249982528 cites W2745745497 @default.
- W4249982528 cites W2748612127 @default.
- W4249982528 cites W2753275354 @default.
- W4249982528 cites W2764150248 @default.
- W4249982528 cites W2781936076 @default.
- W4249982528 cites W2783223151 @default.
- W4249982528 cites W2785191358 @default.
- W4249982528 cites W2785880166 @default.
- W4249982528 cites W2786326339 @default.
- W4249982528 cites W2792182372 @default.
- W4249982528 cites W2809149148 @default.
- W4249982528 cites W2883415937 @default.
- W4249982528 cites W2883993204 @default.
- W4249982528 cites W2885998187 @default.
- W4249982528 cites W2890891746 @default.
- W4249982528 cites W2895382733 @default.
- W4249982528 cites W2896917408 @default.
- W4249982528 cites W2900876668 @default.
- W4249982528 cites W2906789349 @default.
- W4249982528 cites W2908619147 @default.
- W4249982528 cites W2911984236 @default.
- W4249982528 cites W2914425149 @default.
- W4249982528 cites W2917772364 @default.
- W4249982528 cites W2951146532 @default.
- W4249982528 cites W2951847314 @default.
- W4249982528 cites W2953001036 @default.
- W4249982528 cites W2972237750 @default.
- W4249982528 cites W2996894684 @default.
- W4249982528 cites W3009675434 @default.
- W4249982528 cites W3217042883 @default.
- W4249982528 cites W4237517687 @default.
- W4249982528 cites W4238141584 @default.
- W4249982528 cites W4246342009 @default.
- W4249982528 cites W4247185216 @default.
- W4249982528 cites W4249690622 @default.
- W4249982528 cites W4251766850 @default.
- W4249982528 cites W4252494182 @default.
- W4249982528 cites W578586666 @default.
- W4249982528 doi "https://doi.org/10.1002/ange.202004441" @default.
- W4249982528 hasPublicationYear "2020" @default.
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