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• W4250087144 endingPage "1517" @default.
• W4250087144 startingPage "1513" @default.
• W4250087144 abstract "Abstract Regioselective incorporation of a particular functional group into aliphatic sites by direct activation of unreactive C−H bonds is of great synthetic value. Despite advances in radical‐mediated functionalization of C(sp 3 )−H bonds by a hydrogen‐atom transfer process, the site‐selective vinylation of remote C(sp 3 )−H bonds still remains underexplored. Reported herein is a new protocol for the regioselective vinylation of unactivated C(sp 3 )−H bonds. The remote C(sp 3 )−H activation is promoted by a C‐centered radical instead of the commonly used N and O radicals. The reaction possesses high product diversity and synthetic efficiency, furnishing a plethora of synthetically valuable E alkenes bearing tri‐/di‐/mono‐fluoromethyl and perfluoroalkyl groups." @default.
• W4250087144 created "2022-05-12" @default.
• W4250087144 creator A5013289800 @default.
• W4250087144 creator A5020555164 @default.
• W4250087144 creator A5041846457 @default.
• W4250087144 creator A5066001386 @default.
• W4250087144 date "2018-12-28" @default.
• W4250087144 modified "2023-09-30" @default.
• W4250087144 title "Regioselective Vinylation of Remote Unactivated C(sp³)−H Bonds: Access to Complex Fluoroalkylated Alkenes" @default.
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