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- W4250137644 abstract "Pro-blemlos: Die Pro-Cys-Ligation mit einem zuvor gebildeten Prolylselenoester wird vorgestellt (siehe Schema; P=Peptid). In einer vergleichenden Studie erwiesen sich Peptid-α-Selenoester als die besten Acyldonoren; sie steigerten die Reaktionsgeschwindigkeit gegenüber den etablierten Peptid-α-Thioestern um zwei Größenordnungen. Damit gelingt die Ligation auch an Stellen wie Pro-Cys, für die bisher keine Methode verfügbar war. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4250137644 date "2011-10-13" @default.
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- W4250137644 title "Preformed Selenoesters Enable Rapid Native Chemical Ligation at Intractable Sites" @default.
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- W4250137644 doi "https://doi.org/10.1002/ange.201105512" @default.
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