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- W4250465511 abstract "Cyclopalladated azobenzene tetrafluoroborate catalyzes the dimerization of styrene to 2,3-diphenyl-l-butene and the isomerization of allylbenzene. The complex reacts stoichiometrically with various disubstituted alkynes to form 2-phenylcinnolinium tetrafluoroborate derivatives, usually in good yields. Similar reactions occur with cyclopalladated N-substituted benzalimine salts, Disubstituted alkynes, for example, react to form N-substituted isoquinolinium salts. Other cyclopalladated complexes form naphthalene or pentasubstituted cyclopentadiene derivatives, 1,2,3,4-Tetraphenylnaphthalene derivatives have been obtained in modest yields catalytically from iodobenzene derivatives and diphenylacetylene. Vinylic bromides and diphenylacetylene with a palladium catalyst form fulvene derivatives in low yields." @default.
- W4250465511 created "2022-05-12" @default.
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- W4250465511 date "2020-07-24" @default.
- W4250465511 modified "2023-09-23" @default.
- W4250465511 title "Alkene and Alkyne Reactions with Cyclopalladated Organopalladium Complexes" @default.
- W4250465511 doi "https://doi.org/10.1201/9781003066446-15" @default.
- W4250465511 hasPublicationYear "2020" @default.
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