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- W4250522622 abstract "Abstract Radical cations of bis(triarylamine)s, 3 and 4 , in which the triarylamine redox centers are bridged by an ortho ‐phenylene and ortho ‐carborane cluster, respectively, have been prepared to elucidate the difference in intramolecular charge/spin‐transfer (ICT/IST) pathway owing to the two different bridging units affording similar geometrical arrangements between the redox centers. Electrochemistry, absorption spectroscopy, VT‐ESR spectroscopy, and DFT calculations reveal that 3 .+ and 4 .+ are classified into class II and class I mixed‐valence systems, respectively, and therefore, through‐bond and through‐space mechanisms are dominant for the ICT/IST phenomena in 3 .+ and 4 .+ , respectively. Moreover, SQUID measurements for dicationic species provide the fact that virtually no spin‐exchange interaction is observed for spins in 4 2+ , while the antiferromagnetic interaction for spins in 3 2+ , in accordance with the existence of a conjugation pathway for the ortho ‐phenylene bridge." @default.
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- W4250522622 date "2017-11-08" @default.
- W4250522622 modified "2023-10-02" @default.
- W4250522622 title "Recognizing Through-Bond and Through-Space Self-Exchange Charge/Spin Transfer Pathways in Bis(triarylamine) Radical Cations with Similar Geometrical Arrangements" @default.
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- W4250522622 doi "https://doi.org/10.1002/ange.201709874" @default.
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