FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4250701471> ?p ?o ?g. }

• W4250701471 abstract "Abstract. An ion chromatographic method is described for the quantification of the simple alkyl amines: methylamine (MA), dimethylamine (DMA), trimethylamine (TMA), ethylamine (EA), diethylamine (DEA) and triethylamine (TEA), in the ambient atmosphere. Limits of detection (3σ) are in the tens of pmol range for all of these amines, and good resolution is achieved for all compounds except for TMA and DEA. The technique was applied to the analysis of time-integrated samples collected using a micro-orifice uniform deposition impactor (MOUDI) with ten stages for size resolution of particles with aerodynamic diameters between 56 nm and 18 μm. In eight samples from urban and rural continental airmasses, the mass loading of amines consistently maximized on the stage corresponding to particles with aerodynamic diameters between 320 and 560 nm. The molar ratio of amines to ammonium (R3NH+/NH4+) in fine aerosol ranged between 0.005 and 0.2, and maximized for the smallest particle sizes. The size-dependence of the R3NH+/NH4+ ratio indicates differences in the relative importance of the processes leading to the incorporation of amines and ammonia into secondary particles. The technique was also used to make simultaneous hourly online measurements of amines in the gas phase and in fine particulate matter using an Ambient Ion Monitor Ion Chromatograph (AIM-IC). During a ten day campaign in downtown Toronto, DMA, TMA+DEA, and TEA were observed to range from below detection limit to 2.7 ppt in the gas phase. In the particle phase, MAH+ and TMAH++DEAH+ were observed to range from below detection limit up to 15 ng m−3. The presence of detectable levels of amines in the particle phase corresponded to periods with higher relative humidity and higher mass loadings of nitrate. While the hourly measurements made using the AIM-IC provide data that can be used the evaluate the application of gas-particle partitioning models to amines, the strong size-dependence of the R3NH+/NH4+ ratio indicates that using bulk measurements and an assumption of internal mixing may not be appropriate." @default.
• W4250701471 created "2022-05-12" @default.
• W4250701471 creator A5016231702 @default.
• W4250701471 creator A5020157499 @default.
• W4250701471 creator A5051560946 @default.
• W4250701471 creator A5074414172 @default.
• W4250701471 date "2010-11-11" @default.
• W4250701471 modified "2023-09-27" @default.
• W4250701471 title "Size distribution of alkyl amines in continental particulate matter and their online detection in the gas and particle phase" @default.
• W4250701471 cites W1968304087 @default.
• W4250701471 cites W1969061516 @default.
• W4250701471 cites W1971715420 @default.
• W4250701471 cites W1973000930 @default.
• W4250701471 cites W1975574886 @default.
• W4250701471 cites W1979883270 @default.
• W4250701471 cites W1986326162 @default.
• W4250701471 cites W1992290252 @default.
• W4250701471 cites W1993267273 @default.
• W4250701471 cites W1994245392 @default.
• W4250701471 cites W1995182002 @default.
• W4250701471 cites W1995760349 @default.
• W4250701471 cites W2000636897 @default.
• W4250701471 cites W2002299817 @default.
• W4250701471 cites W2005686382 @default.
• W4250701471 cites W2017496924 @default.
• W4250701471 cites W2026275622 @default.
• W4250701471 cites W2031904064 @default.
• W4250701471 cites W2033284165 @default.
• W4250701471 cites W2033943398 @default.
• W4250701471 cites W2034989340 @default.
• W4250701471 cites W2036889881 @default.
• W4250701471 cites W2041137627 @default.
• W4250701471 cites W2041940393 @default.
• W4250701471 cites W2043063888 @default.
• W4250701471 cites W2047220791 @default.
• W4250701471 cites W2050011851 @default.
• W4250701471 cites W2050265989 @default.
• W4250701471 cites W2053492064 @default.
• W4250701471 cites W2056715233 @default.
• W4250701471 cites W2065619023 @default.
• W4250701471 cites W2066195200 @default.
• W4250701471 cites W2066243315 @default.
• W4250701471 cites W2067064657 @default.
• W4250701471 cites W2076462014 @default.
• W4250701471 cites W2085301075 @default.
• W4250701471 cites W2093124063 @default.
• W4250701471 cites W2101952436 @default.
• W4250701471 cites W2113076595 @default.
• W4250701471 cites W2115798074 @default.
• W4250701471 cites W2121240252 @default.
• W4250701471 cites W2132869159 @default.
• W4250701471 cites W2137630955 @default.
• W4250701471 cites W2139167000 @default.
• W4250701471 cites W2155287037 @default.
• W4250701471 cites W2156534742 @default.
• W4250701471 cites W2168410377 @default.
• W4250701471 cites W291553663 @default.
• W4250701471 cites W4238094617 @default.
• W4250701471 cites W4256522341 @default.
• W4250701471 doi "https://doi.org/10.5194/acpd-10-27435-2010" @default.
• W4250701471 hasPublicationYear "2010" @default.
• W4250701471 type Work @default.
• W4250701471 citedByCount "0" @default.
• W4250701471 crossrefType "posted-content" @default.
• W4250701471 hasAuthorship W4250701471A5016231702 @default.
• W4250701471 hasAuthorship W4250701471A5020157499 @default.
• W4250701471 hasAuthorship W4250701471A5051560946 @default.
• W4250701471 hasAuthorship W4250701471A5074414172 @default.
• W4250701471 hasBestOaLocation W42507014711 @default.
• W4250701471 hasConcept C107872376 @default.
• W4250701471 hasConcept C111368507 @default.
• W4250701471 hasConcept C113196181 @default.
• W4250701471 hasConcept C119128265 @default.
• W4250701471 hasConcept C127313418 @default.
• W4250701471 hasConcept C147789679 @default.
• W4250701471 hasConcept C178790620 @default.
• W4250701471 hasConcept C185592680 @default.
• W4250701471 hasConcept C187530423 @default.
• W4250701471 hasConcept C24245907 @default.
• W4250701471 hasConcept C2776149385 @default.
• W4250701471 hasConcept C2777449572 @default.
• W4250701471 hasConcept C2778517922 @default.
• W4250701471 hasConcept C2778678469 @default.
• W4250701471 hasConcept C2779345167 @default.
• W4250701471 hasConcept C2779870022 @default.
• W4250701471 hasConcept C2780263894 @default.
• W4250701471 hasConcept C2780825948 @default.
• W4250701471 hasConcept C43617362 @default.
• W4250701471 hasConceptScore W4250701471C107872376 @default.
• W4250701471 hasConceptScore W4250701471C111368507 @default.
• W4250701471 hasConceptScore W4250701471C113196181 @default.
• W4250701471 hasConceptScore W4250701471C119128265 @default.
• W4250701471 hasConceptScore W4250701471C127313418 @default.
• W4250701471 hasConceptScore W4250701471C147789679 @default.
• W4250701471 hasConceptScore W4250701471C178790620 @default.
• W4250701471 hasConceptScore W4250701471C185592680 @default.
• W4250701471 hasConceptScore W4250701471C187530423 @default.
• W4250701471 hasConceptScore W4250701471C24245907 @default.
• W4250701471 hasConceptScore W4250701471C2776149385 @default.
• W4250701471 hasConceptScore W4250701471C2777449572 @default.

• next