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- W4250711329 abstract "A new category of crystalline polymer electrolyte prepared by the supramolecular self-assembly of polyethylene oxide (PEO), α-cyclodextrin (α-CD), and LiAsF6 is reported. The polymer electrolyte consists of the nanochannels formed by α-CDs in which the PEO/Li+ complexes are confined. The nanochannels formed by α-CD provide the pathway for the directional motion of Li+ ions and at the same time prevent the access of the anions by size exclusion, resulting in good separation of the Li+ ions and the anions. The conductivity of the reported material is 30 times higher than that of the comparable PEO/Li+ complex crystal at room temperature. By using state-of-art solid-state NMR spectroscopy, the structure and dynamics of the material were investigated in detail. The dynamics of the Li+ ions was studied and correlated to the ionic conductivity of the material." @default.
- W4250711329 created "2022-05-12" @default.
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- W4250711329 date "2014-03-05" @default.
- W4250711329 modified "2023-10-18" @default.
- W4250711329 title "Transferring Lithium Ions in Nanochannels: A PEO/Li<sup>+</sup>Solid Polymer Electrolyte Design" @default.
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- W4250711329 doi "https://doi.org/10.1002/ange.201307423" @default.
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