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- W4250870138 abstract "Thermosetting resin changes from liquid to solid through cure reaction induced by temperature increase. The viscosity of resin in the fluid state varies sequentially depending on the temperature condition. For inappropriate temperature condition, defects such as unfilled state of the resin and excessive outflow of adhesive are generated. Therefore, it is important to model the viscosity considering the degree of the cure reaction of the resin. Familiar single-reaction models presented in the many previous studies can not be applied to multiple-reaction one where their relationship must be considered. In our previous study, the reaction behavior with two reactions was modeled with considering the diffusion control for reaction which represents the decrease of the reaction rate by vitrification. In this study, the viscosity prediction model using the two-step reaction model was constructed. The results showed that it was important to incorporate the temperature dependence of viscosity increase for degree of reaction which is not considered for a general viscosity model in order to predict the viscosity in a wide temperature range. In addition, the measured viscosity values were well reproduced by our novel theoretical model considering the temperature dependence of viscosity increase for degree of reaction using the fractional function." @default.
- W4250870138 created "2022-05-12" @default.
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- W4250870138 date "2021-01-01" @default.
- W4250870138 modified "2023-10-16" @default.
- W4250870138 title "Viscosity Modeling for Thermosetting Resin Having Two-step Reaction Considering Temperature Dependence of Viscosity Increase for Degree of Reaction" @default.
- W4250870138 doi "https://doi.org/10.1299/jsmemecj.2021.j031-26" @default.
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