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- W4250871682 abstract "[463-71-8] CCl2S (MW 114.98) (very electrophilic reagent capable of forming isothiocyanates with amines;1 used in forming various heterocycles;12 in combination with phosphorus reagents, capable of forming cis- and trans-alkenes from cyclic thiocarbonates (Corey–Winter alkenation);22 dienophile in Diels–Alder reactions25) Physical Data: bp 73 °C; d 1.508 g cm−3. Solubility: sol most organic solvents; decomposes in H2O and alcoholic solvents. Form Supplied in: red-orange liquid; widely available. Handling, Storage, and Precautions: wear appropriate safety equipment. Use only in a chemical fume hood; keep container tightly closed; unpleasant odor. Moisture sensitive; store under nitrogen; refrigerate. Highly toxic; may be fatal if inhaled, swallowed, or absorbed through skin; corrosive; lachrymator." @default.
- W4250871682 created "2022-05-12" @default.
- W4250871682 creator A5084614356 @default.
- W4250871682 date "2001-04-15" @default.
- W4250871682 modified "2023-09-25" @default.
- W4250871682 title "Thiophosgene" @default.
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- W4250871682 doi "https://doi.org/10.1002/047084289x.rt103" @default.
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