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- W4250873361 abstract "The {N2} unit of aryldiazonium salts undergoes unusually facile triple-bond metathesis on treatment with molybdenum or tungsten alkylidyne ate complexes endowed with triphenylsilanolate ligands. The reaction transforms the alkylidyne unit into a nitrile and the aryldiazonium entity into an imido ligand on the metal center, as unambiguously confirmed by X-ray structure analysis of two representative examples. A tungsten nitride ate complex is shown to react analogously. Since the bonding situation of an aryldiazonium salt is similar to that of metal complexes with end-on-bound dinitrogen, in which {N2}→M σ donation is dominant and electron back donation minimal, the metathesis described herein is thought to be a conceptually novel strategy toward dinitrogen cleavage devoid of any redox steps and, therefore, orthogonal to the established methods." @default.
- W4250873361 created "2022-05-12" @default.
- W4250873361 creator A5049975297 @default.
- W4250873361 creator A5054667122 @default.
- W4250873361 date "2015-09-02" @default.
- W4250873361 modified "2023-10-03" @default.
- W4250873361 title "The Triple-Bond Metathesis of Aryldiazonium Salts: A Prospect for Dinitrogen Cleavage" @default.
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- W4250873361 doi "https://doi.org/10.1002/ange.201506546" @default.
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