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- W4251036001 abstract "Genistein isoflavone is shown to exist in two different conformations which are the 90° completely twisted geometry and the 50° less twisted one. Specific interactions with the solvent cage as well as self-association processes seem shifting the isoflavone from the perpendicular conformation towards the less twisted one. The theoretical simulation, using analytical atom–atom pair potential, predicts a self-dimer in a slipped non-sandwich, face to river, perpendicular structure. From the UV–visible photophysics investigations it is revealed that monomeric species cannot exist alone even at very low solute concentration (∼10−6 M), the self-association process occurs already in this concentration range." @default.
- W4251036001 created "2022-05-12" @default.
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- W4251036001 date "1983-06-01" @default.
- W4251036001 modified "2023-10-18" @default.
- W4251036001 title "Molecular associations" @default.
- W4251036001 doi "https://doi.org/10.1016/0010-4655(83)90014-0" @default.
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