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- W4251126105 abstract "Abstract 1,3‐N,O‐chelated complexes of Rh I and Ir I cooperatively and reversibly stabilized the B−H bond of HBCy 2 to afford six‐membered metallaheterocycles (M=Rh ( 7 ) or Ir ( 8 )) having a δ‐[M]⋅⋅⋅H‐B agostic interaction. Treatment of these Shimoi‐type borane adducts 7 or 8 with both an aldehyde and an alkene resulted in chemoselective aldehyde hydroboration and reformation of the 1,3‐N,O‐chelated starting material. The observed chemoselectivity is inverted from that of free HBCy 2 , which is selective for alkene hydroboration." @default.
- W4251126105 created "2022-05-12" @default.
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- W4251126105 date "2016-02-05" @default.
- W4251126105 modified "2023-10-03" @default.
- W4251126105 title "Capturing HBCy<sub>2</sub>: Using N,O-Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration" @default.
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- W4251126105 doi "https://doi.org/10.1002/ange.201511448" @default.
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