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- W4251181875 abstract "Solvent extraction, potentiometry, and calorimetry have been used to determine the thermodynamic parameters of the formation of the monofluoride complex of the trivalent lanthanide ions at 25°C. and an ionic strength of 1M (NaClO4). The enthalpies were all endothermic, ranging from 4.0 to 9.5 Kcal./mole; consequently, the large, positive entropies, ranging from 25 to 48 cal./°C./mole, explain the high stability constants. This large entropy results from the decrease in overall water structure when the fluoride ion is complexed. The difference in the enthalpies of formation of LnF2+ and LnAc2+ can possibly be explained by a difference in covalence for Ln-F and Ln-O bonds." @default.
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- W4251181875 date "1967-06-01" @default.
- W4251181875 modified "2023-10-15" @default.
- W4251181875 title "Thermodynamic Parameters of Fluoride Complexes of the Lanthanides" @default.
- W4251181875 doi "https://doi.org/10.1021/ba-1967-0071.ch010" @default.
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