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- W4251189077 abstract "The storage of solar energy in battery systems is pivotal for a sustainable society, which faces many challenges. Herein, a Zn-air battery is constructed with two cathodes of poly(1,4-di(2-thienyl))benzene (PDTB) and TiO2 grown on carbon papers to sandwich a Zn anode. The PDTB cathode is illuminated in a discharging process, in which photoelectrons are excited into the conduction band of PDTB to promote oxygen reduction reaction (ORR) and raise the output voltage. In a reverse process, holes in the valence band of the illuminated TiO2 cathode are driven for the oxygen evolution reaction (OER) by an applied voltage. A record-high discharge voltage of 1.90 V and an unprecedented low charge voltage of 0.59 V are achieved in the photo-involved Zn-air battery, regardless of the equilibrium voltage. This work offers an innovative pathway for photo-energy utilization in rechargeable batteries." @default.
- W4251189077 created "2022-05-12" @default.
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- W4251189077 date "2020-08-13" @default.
- W4251189077 modified "2023-10-03" @default.
- W4251189077 title "Photo‐excited Oxygen Reduction and Oxygen Evolution Reactions Enable a High‐Performance Zn–Air Battery" @default.
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- W4251189077 doi "https://doi.org/10.1002/anie.202005929" @default.
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