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- W4251192783 abstract "The term ionic polymerization basically involves the chemistry of heterolytic cleavage of chemical bonds, as opposed to the homolytic reactions that characterize the well-known free-radical polymerization mechanism. Hence, essential and profound differences exist between these two mechanisms of polymerization. Although these differences are also found between radical and ionic mechanisms in ordinary reactions, they exert a much more drastic influence on the result, that is, the growth of a long chain molecule to macro dimensions. Thus, one would expect that the two mechanisms could lead to quite different results in most simple reactions, in terms of rate, yield, or mode of the reaction. In the case of polymerization, however, such differences, can, in fact, decide whether any high polymer is obtained at all. The differences between the homolytic and heterolytic mechanisms of polymerization are reflected in the influence of the following factors on the course of the reaction: 1. The effect of" @default.
- W4251192783 created "2022-05-12" @default.
- W4251192783 creator A5023716667 @default.
- W4251192783 date "1985-09-25" @default.
- W4251192783 modified "2023-10-13" @default.
- W4251192783 title "Anionic Polymerization" @default.
- W4251192783 doi "https://doi.org/10.1021/bk-1985-0285.ch003" @default.
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