Matches in SemOpenAlex for { <https://semopenalex.org/work/W4251254360> ?p ?o ?g. }
- W4251254360 endingPage "23760" @default.
- W4251254360 startingPage "23756" @default.
- W4251254360 abstract "Abstract Force‐selective mechanochemical reactions may be important for applications in polymer mechanochemistry, yet it is difficult to achieve such reactions. This paper reports that cis ‐N‐phthalimidoaziridine incorporated into a macromolecular backbone undergoes migration of N‐phthalimido group to afford imine under mechanochemical condition and not thermal one. The imine is further hydrolyzed by water bifurcating into amine and aldehyde. These structural transformations are confirmed by 1 H NMR and FT‐IR spectroscopic analyses. Computational simulations are conducted for the aziridine mechanophore to propose the mechanism of reaction and define the substrate scope of reaction." @default.
- W4251254360 created "2022-05-12" @default.
- W4251254360 creator A5086588733 @default.
- W4251254360 creator A5090227951 @default.
- W4251254360 date "2021-09-29" @default.
- W4251254360 modified "2023-09-26" @default.
- W4251254360 title "Mechanical Force for the Transformation of Aziridine into Imine" @default.
- W4251254360 cites W1065315841 @default.
- W4251254360 cites W1251317203 @default.
- W4251254360 cites W1978163738 @default.
- W4251254360 cites W1980781458 @default.
- W4251254360 cites W2003490619 @default.
- W4251254360 cites W2007927363 @default.
- W4251254360 cites W2010165618 @default.
- W4251254360 cites W2016569354 @default.
- W4251254360 cites W2023974158 @default.
- W4251254360 cites W2043412192 @default.
- W4251254360 cites W2047182279 @default.
- W4251254360 cites W2051769448 @default.
- W4251254360 cites W2062490158 @default.
- W4251254360 cites W2126501716 @default.
- W4251254360 cites W2130976196 @default.
- W4251254360 cites W2150871580 @default.
- W4251254360 cites W2161792378 @default.
- W4251254360 cites W2412336775 @default.
- W4251254360 cites W2472337882 @default.
- W4251254360 cites W2525539600 @default.
- W4251254360 cites W2553133555 @default.
- W4251254360 cites W2586830724 @default.
- W4251254360 cites W2594319158 @default.
- W4251254360 cites W2598318433 @default.
- W4251254360 cites W2738342839 @default.
- W4251254360 cites W2760584905 @default.
- W4251254360 cites W2763552817 @default.
- W4251254360 cites W2804430736 @default.
- W4251254360 cites W2808341587 @default.
- W4251254360 cites W2883647989 @default.
- W4251254360 cites W2888092820 @default.
- W4251254360 cites W2896287970 @default.
- W4251254360 cites W2937907080 @default.
- W4251254360 cites W2957479982 @default.
- W4251254360 cites W2963594502 @default.
- W4251254360 cites W2968635115 @default.
- W4251254360 cites W2972445890 @default.
- W4251254360 cites W2997035103 @default.
- W4251254360 cites W2999615405 @default.
- W4251254360 cites W2999783969 @default.
- W4251254360 cites W3000274760 @default.
- W4251254360 cites W3012442263 @default.
- W4251254360 cites W3016433448 @default.
- W4251254360 cites W3043565908 @default.
- W4251254360 cites W3046425087 @default.
- W4251254360 cites W3048781706 @default.
- W4251254360 cites W3084096626 @default.
- W4251254360 cites W3088695401 @default.
- W4251254360 cites W3089638891 @default.
- W4251254360 cites W3122266231 @default.
- W4251254360 cites W3133485826 @default.
- W4251254360 cites W4251479314 @default.
- W4251254360 doi "https://doi.org/10.1002/ange.202109358" @default.
- W4251254360 hasPublicationYear "2021" @default.
- W4251254360 type Work @default.
- W4251254360 citedByCount "2" @default.
- W4251254360 countsByYear W42512543602022 @default.
- W4251254360 crossrefType "journal-article" @default.
- W4251254360 hasAuthorship W4251254360A5086588733 @default.
- W4251254360 hasAuthorship W4251254360A5090227951 @default.
- W4251254360 hasConcept C131779359 @default.
- W4251254360 hasConcept C161790260 @default.
- W4251254360 hasConcept C178790620 @default.
- W4251254360 hasConcept C180577832 @default.
- W4251254360 hasConcept C185592680 @default.
- W4251254360 hasConcept C188027245 @default.
- W4251254360 hasConcept C204389451 @default.
- W4251254360 hasConcept C2776573223 @default.
- W4251254360 hasConcept C2778544067 @default.
- W4251254360 hasConcept C2779825165 @default.
- W4251254360 hasConcept C2780378348 @default.
- W4251254360 hasConcept C32909587 @default.
- W4251254360 hasConcept C46305533 @default.
- W4251254360 hasConcept C508816927 @default.
- W4251254360 hasConcept C55493867 @default.
- W4251254360 hasConcept C65024703 @default.
- W4251254360 hasConcept C93275456 @default.
- W4251254360 hasConceptScore W4251254360C131779359 @default.
- W4251254360 hasConceptScore W4251254360C161790260 @default.
- W4251254360 hasConceptScore W4251254360C178790620 @default.
- W4251254360 hasConceptScore W4251254360C180577832 @default.
- W4251254360 hasConceptScore W4251254360C185592680 @default.
- W4251254360 hasConceptScore W4251254360C188027245 @default.
- W4251254360 hasConceptScore W4251254360C204389451 @default.
- W4251254360 hasConceptScore W4251254360C2776573223 @default.
- W4251254360 hasConceptScore W4251254360C2778544067 @default.
- W4251254360 hasConceptScore W4251254360C2779825165 @default.
- W4251254360 hasConceptScore W4251254360C2780378348 @default.
- W4251254360 hasConceptScore W4251254360C32909587 @default.
- W4251254360 hasConceptScore W4251254360C46305533 @default.
- W4251254360 hasConceptScore W4251254360C508816927 @default.