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• W4251274908 endingPage "142" @default.
• W4251274908 startingPage "101" @default.
• W4251274908 abstract "The oxidation of alkyl sp3C-H bonds adjacent to unsaturated carbon atoms (carbon functional groups) belongs to the secondary functionalization. Usually, there are two kinds of sp3C-H bonds adjacent to unsaturated carbon atoms according to their BDE and pKa values. One is noninert sp3C-H bonds with low BDE but high pKa, and the other is active sp3C-H bonds with low pKa. This chapter discusses their oxidations involving the cleavage of C-H bonds separately. The traditional strategy is to employ a powerful metal reagent as an oxidant in the transformation of sp3C-H bonds to sp3C-O bonds. It is known that both allylic and benzylic sp3C-H bonds can be cleaved through either free radical process or C-H activation in their transformations. On the other hand, the acidic α-sp3C-H bonds of carbonyl compounds can be attacked directly by electrophilic species. These approaches are still available in their halogenations." @default.
• W4251274908 created "2022-05-12" @default.
• W4251274908 date "2017-02-18" @default.
• W4251274908 modified "2023-10-14" @default.
• W4251274908 title "Oxidation of Alkyl sp ³ C─H Bond Adjacent to Unsaturated Carbon Atom" @default.
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