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- W4251443437 abstract "Wie kann die konkurrierende β-Eliminierung der Abgangsgruppen von aus Hexapyranosen erhaltenen organometallischen Reagentien minimiert werden? Antwort: Die Zugabe katalytischer Mengen an Nickel(II)-iodid bei der reduktiven Samarierung von anomeren 2-Pyridylsulfonen genügt. Das Ergebnis ist eine schnelle, effiziente und hoch stereoselektive Synthese von C-Glycosylverbindungen, etwa von 3 aus dem Sulfon 1 (2-Py=2-Pyridyl) und dem Aldehyd 2." @default.
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- W4251443437 date "2000-11-17" @default.
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- W4251443437 title "Reductive Samariation of Anomeric 2-Pyridyl Sulfones with Catalytic Nickel: An Unexpected Improvement in the Synthesis of 1,2-trans-Diequatorial C-Glycosyl Compounds" @default.
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- W4251443437 doi "https://doi.org/10.1002/1521-3757(20001117)112:22<4277::aid-ange4277>3.0.co;2-3" @default.
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