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- W4251579488 abstract "Die Carbonylverbindungen (I) lassen sich durch Addition von 1-Lithio-1-(trimethylsilyl)- ethylen und anschließende Simmons-Smith-Cyclopropanierung über die Alkohole (II) in die Cyclopropylcarbinole (III) [bis auf (IIIc)] überführen, von denen (IIIa) und (IIIb) bereits bei der chromatographischen Reinigung dehydratisiert werden [die Dehydratisierung der Carbinole (III) in Benzol bei 20°C in Gegenwart von p-Toluolsulfonsäure erfolgt ohne Umlagerung (Produkt-Ausb. 52-75%)]." @default.
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- W4251579488 date "1983-07-26" @default.
- W4251579488 modified "2023-09-30" @default.
- W4251579488 title "ChemInform Abstract: SILICON IN ORGANIC SYNTHESIS - 17. CYCLOPENTANNULATION BY THERMOLYSIS OF (1-TRIMETHYLSILYLCYCLOPROPYL)ETHYLENES - THE 1-TRIMETHYLSILYLCYCLOPROPYL ANION" @default.
- W4251579488 cites W2314375247 @default.
- W4251579488 doi "https://doi.org/10.1002/chin.198330293" @default.
- W4251579488 hasPublicationYear "1983" @default.
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