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- W4251715809 abstract "D.c. polarography and cyclic voltammetry of the reduction of cobalt(II) complex with the tridentate imine ligand 2,2′,2″-terpyridine were carried out in acetonitrile solutions. The cobalt(II) complex gave a four step reduction wave at DME when tetra-n-butyl ammonium perchlorate was used as supporting electrolyte. The first two steps were found to be diffusion controlled one-electron reduction processes. The electrode processes led to the formation of the low valence states Co(terpy)2+ and Co(terpy)20, the latter not being obtained in aqueous solution. Comparisons are made with Fe(terpy)22+; the results are in agreement with the hypothesis suggested in explaining the behaviour of Fe(terpy)22+." @default.
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- W4251715809 date "1973-08-25" @default.
- W4251715809 modified "2023-10-18" @default.
- W4251715809 title "Low valence states of metal chelates III. Bis(2,2′,2″-terpyridine) cobalt(II) perchlorate" @default.
- W4251715809 doi "https://doi.org/10.1016/0368-1874(73)87048-0" @default.
- W4251715809 hasPublicationYear "1973" @default.
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