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• W4251742317 endingPage "14730" @default.
• W4251742317 startingPage "14726" @default.
• W4251742317 abstract "Metal-catalyzed reactions of amides proceeding via metal insertion into the NCO bond are severely underdeveloped due to resonance stabilization of the amide bond. Herein we report the first Heck reaction of amides proceeding via highly chemoselective NCO cleavage catalyzed by Pd0 utilizing amide bond ground-state destabilization. Conceptually, this transformation provides access to a myriad of metal-catalyzed transformations of amides via metal insertion/decarbonylation." @default.
• W4251742317 created "2022-05-12" @default.
• W4251742317 creator A5068601986 @default.
• W4251742317 creator A5070628814 @default.
• W4251742317 date "2015-10-12" @default.
• W4251742317 modified "2023-10-18" @default.
• W4251742317 title "General Olefin Synthesis by the Palladium-Catalyzed Heck Reaction of Amides: Sterically Controlled Chemoselective NC Activation" @default.
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• W4251742317 doi "https://doi.org/10.1002/ange.201507776" @default.
• W4251742317 hasPublicationYear "2015" @default.
• W4251742317 type Work @default.

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