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• W4251832023 endingPage "12264" @default.
• W4251832023 startingPage "12260" @default.
• W4251832023 abstract "We have found that an organic molecule as simple as p-anisaldehyde efficiently catalyzes the intermolecular atom-transfer radical addition (ATRA) of a variety of haloalkanes onto olefins, one of the fundamental carbon–carbon bond-forming transformations in organic chemistry. The reaction requires exceptionally mild reaction conditions to proceed, as it occurs at ambient temperature and under illumination by a readily available fluorescent light bulb. Initial investigations support a mechanism whereby the aldehydic catalyst photochemically generates the reactive radical species by sensitization of the organic halides by an energy-transfer pathway." @default.
• W4251832023 created "2022-05-12" @default.
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• W4251832023 date "2014-09-22" @default.
• W4251832023 modified "2023-10-17" @default.
• W4251832023 title "Photo-Organocatalysis of Atom-Transfer Radical Additions to Alkenes" @default.
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• W4251832023 doi "https://doi.org/10.1002/ange.201406450" @default.
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