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- W4251910463 endingPage "13696" @default.
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- W4251910463 abstract "This work demonstrates how photoredox-mediated C(sp3)−H activation through radical translocation can be combined with asymmetric catalysis. Upon irradiation with visible light, α,β-unsaturated N-acylpyrazoles react with N-alkoxyphthalimides in the presence of a rhodium-based chiral Lewis acid catalyst and the photosensitizer fac-[Ir(ppy)3] to provide a C−C bond-formation product with high enantioselectivity (up to 97 % ee) and, where applicable, with some diastereoselectivity (3.0:1 d.r.). Mechanistically, the synthetic strategy exploits a radical translocation (1,5-hydrogen transfer) from an oxygen-centered to a carbon-centered radical with a subsequent stereocontrolled radical alkene addition." @default.
- W4251910463 created "2022-05-12" @default.
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- W4251910463 date "2016-09-26" @default.
- W4251910463 modified "2023-10-18" @default.
- W4251910463 title "Catalytic Asymmetric Csp3 −H Functionalization under Photoredox Conditions by Radical Translocation and Stereocontrolled Alkene Addition" @default.
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- W4251910463 doi "https://doi.org/10.1002/ange.201607305" @default.
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