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- W4251956632 abstract "We recently (2) reported that under conditions of coal conversion (tetralin, 400°) several diarylalkanes undergo carbon-carbon cleavage, and that the scission of carbon-carbon bonds must therefore be considered as an important process in asphaltene formation (3). We also reported (2) that vitrinite (from Illinois No. 6 coal) was a better hydrogen transfer agent than tetralin itself for the hydrogenolysis of 1,1,2-triphenylethane to diphenylmethane and toluene. We have now extended these studies to establish a) that vitrinite is indeed a better hydrogen donor than tetralin toward several organic structures; b) that tetralin, in addition to its function as a hydrogen donor, can undergo certain other reactions with coal and coal-like structures which involve both carbon-carbon bond formation and bond cleavage. A Comparison of Tetralin and Vitrinite as H-donors When 1,2-diphenyl-1-p-tolylethane is heated at 400° (either in glass capillaries or in stainless steel tubes) with an excess of tetralin, the major products are" @default.
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- W4251956632 date "1978-06-01" @default.
- W4251956632 modified "2023-09-26" @default.
- W4251956632 title "Isotopic Studies of Thermally Induced Reactions of Coal and Coal-Like Structures" @default.
- W4251956632 doi "https://doi.org/10.1021/bk-1978-0071.ch012" @default.
- W4251956632 hasPublicationYear "1978" @default.
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