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- W4251991099 abstract "A novel class of crystalline, microporous aluminophosphate phases has been discovered. It represents the first class of molecular sieves with framework oxide compositions free of silica. The new class of materials encompasses some fourteen reported three-dimensional microporous framework structures, and six two-dimensional layer-type structures. The three-dimensional structures include structural analogues of the zeolites sodalite and erionite-offretite. The novel phases can be synthesized hydrothermally in the presence of organic amines and quaternary ammonium templates. The template is entrapped or clathrated within the crystallizing aluminophosphate network. After thermal decomposition of the template the three-dimensional molecular sieves have the general composition of Al2O3·1.0± 0.2 P2O5. The various structures exhibit intracrystalline adsorption pore volumes from 0.04 to 0.35 cm3/g, and pore sizes from 0.3 to 0.8nm. The aluminophosphate frameworks are hydrophilic." @default.
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- W4251991099 date "1983-05-17" @default.
- W4251991099 modified "2023-10-15" @default.
- W4251991099 title "Aluminophosphate Molecular Sieves: A New Class of Microporous Crystalline Inorganic Solids" @default.
- W4251991099 doi "https://doi.org/10.1021/bk-1983-0218.ch005" @default.
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