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- W4252006543 abstract "The general theory of transformation kinetics is largely confined to isothermal reactions. Several attempts have however been made to apply that theory to non-isothermal nucleation and growth transformations as well. Unfortunately, this has lead to some confusion and misunderstandings when thermal analysis experiments, such as DSC and DTA, associated with Kissinger- or Ozawa-like relationships, are used for the extraction of the kinetic parameters of the non-isothermal transformations. The present Part II of this paper widens the scope of the discussed issues, assesses the correct way of applying the theory of isothermal kinetics to non-isothermal transformations, stresses the sources of confusion and points to the mathematical and physical errors that commonly appear in the literature. It is shown that only `site saturated' transformations, i.e. those where the nucleation rate is zero, can be properly analyzed. The general non-isothermal equation for the fraction transformed is proven to be the sound and sole foundation for the correct deduction of the transformation kinetic parameters." @default.
- W4252006543 created "2022-05-12" @default.
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- W4252006543 date "1998-12-01" @default.
- W4252006543 modified "2023-10-14" @default.
- W4252006543 title "Application of thermal analysis methods to nucleation and growth transformation kinetics, Part II" @default.
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- W4252006543 doi "https://doi.org/10.1016/s0040-6031(98)00505-x" @default.
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