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- W4252159295 abstract "Abstract Antiaromaticity, as introduced in 1965, usually refers to monocyclic systems with 4 n π electrons. This concept was extended to all‐metal molecules after the observation of Li 3 Al 4 − in the gas phase. However, the solid‐phase counterparts have not been documented to date. Herein, we describe a series of all‐metal antiaromatic anions, [Ln( η 4 ‐Sb 4 ) 3 ] 3− (Ln=La, Y, Ho, Er, Lu), which were isolated as the K([2.2.2]crypt) salts and identified by single‐crystal X‐ray diffraction. Based on the results obtained from the chemical bonding analysis, multicenter indices, and the electron‐counting rule, we conclude that the core [Ln( η 4 ‐Sb 4 ) 3 ] 3− fragment of the crystal has three locally π‐antiaromatic Sb 4 fragments. This complex represents the first locally π‐antiaromatic all‐metal system in the solid state, which is stabilized by interactions of the three π‐antiaromatic units with the central metal atom." @default.
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- W4252159295 date "2016-04-05" @default.
- W4252159295 modified "2023-09-28" @default.
- W4252159295 title "All‐Metal Antiaromaticity in Sb<sub>4</sub>‐Type Lanthanocene Anions" @default.
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- W4252159295 doi "https://doi.org/10.1002/ange.201600706" @default.
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