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- W4252178198 abstract "Zwei Arten von Chiralität (zentral⇄axial) wurden bei der Synthese von TAN-1085 in drei Chiralitätstransferschritten (A–C im Schema; R1, R2: sperrige Gruppen) transkribiert. Die zentrale Chiralität einer Sulfinylgruppe induzierte die axiale Chiralität eines Styrolderivats, diese wiederum die axiale Chiralität eines Biarylintermediats und diese schließlich die Chiralität der beiden stereogenen Zentren im Aglycon von TAN-1085. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4252178198 date "2009-07-15" @default.
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- W4252178198 title "Stereochemical Relay via Axially Chiral Styrenes: Asymmetric Synthesis of the Antibiotic TAN‐1085" @default.
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