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• W4252182410 abstract "The standard enthalpies of formation of some 3d transition metal silicides have been measured by high temperature direct synthesis calorimetry at 1473±2 K. The following results, in kJ (mole of atoms)−1, are reported: ScSi: (−82.3±2.1); TiSi: (−72.6±1.9); Ti5Si3: (−73.8±2.0); Ti5Si4: (−78.5±2.1); V5Si3: (−59.0±2.0); V3Si: (−46.4±1.5); Cr5Si3: (−33.6±1.0); Cr3Si: (−27.2±1.1); CrSi: (−34.2±1.6); Mn5Si3: (−34.0±1.2); MnSi: (−39.4±1.7); FeSi: (−38.6±1.8); CoSi: (−49.3±1.3); Co2Si: (−37.9±2.0); CoSi2 (−34.9±1.1); Ni2Si (−50.6±1.7); Ni5Si2: (−45.1±1.4). The results are compared with some earlier values obtained by calorimetry or derived from EMF or vapor pressure measurements. They are also compared with predicted values from the semi-empirical model of Miedema and coworkers and with available enthalpies of formation of transition metal germanides and aluminides." @default.
• W4252182410 created "2022-05-12" @default.
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• W4252182410 date "1998-03-01" @default.
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• W4252182410 title "Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry" @default.
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• W4252182410 doi "https://doi.org/10.1016/s0925-8388(97)00528-8" @default.
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