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• W4252422953 endingPage "6009" @default.
• W4252422953 startingPage "6005" @default.
• W4252422953 abstract "Abstract In analogy to the classical reaction of C−B bonds with peroxides, the first oxidative functionalization of aminoboranes through a 1,2‐N migration was realized. Readily available aliphatic nitro compounds are thereby transformed into N‐ and O‐functionalized hydroxylamines in a single synthetic operation. Addition of hazardous peroxides is avoided. Instead, the insertion of O 2 , as the terminal oxidant, into Zn−C bonds provides the necessary peroxides. The required zinc organyls, in turn, are formed through a boron‐to‐zinc exchange, from an organoboronic ester byproduct of the nitro‐to‐aminoborane transformation." @default.
• W4252422953 created "2022-05-12" @default.
• W4252422953 creator A5008964244 @default.
• W4252422953 creator A5020065101 @default.
• W4252422953 creator A5068079659 @default.
• W4252422953 date "2018-04-19" @default.
• W4252422953 modified "2023-10-14" @default.
• W4252422953 title "O₂-Mediated Oxidation of Aminoboranes through 1,2-N Migration" @default.
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• W4252422953 doi "https://doi.org/10.1002/ange.201803168" @default.
• W4252422953 hasPublicationYear "2018" @default.
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