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- W4252512478 abstract "To develop the new-type poly(L-lactide)-based biomedical material having a wettable surface, the synthesis of poly(L-lactide) with one terminal D-glucose residue was investigated. After the hydroxyl group at 1-C of α-tetrabenzyl glucose, α-Glc(Bzl)4, was converted to the corresponding potassium alkoxide by using potassium tert-butoxide, L-lactide (L-LA) was polymerized in the presence of α-Glc(Bzl)4-OK as an initiator in tetrahydrofuran at room temperature to prepare α-Glc(Bzl)4-polyLA. Subsequently, the removal of O-protecting benzyl groups in the terminal α-Glc(Bzl)4 residue was carried out by hydrogenolysis with Pd/C to obtain the objective D-glucose-end-capped polyLA, α-Glc-polyLA. The wettability of surface of the α-Glc-polyLA material is discussed using the difference of the dynamic contact angle between a α-Glc-polyLA/homopolyLA blend film and a film of the polyLA homopolymer." @default.
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- W4252512478 date "2001-12-01" @default.
- W4252512478 modified "2023-09-25" @default.
- W4252512478 title "Synthesis of Poly(L-lactide) with One Terminal D-Glucose Residue and Wettability of Its Film Surface" @default.
- W4252512478 doi "https://doi.org/10.1002/1616-5195(20011201)1:9<371::aid-mabi371>3.3.co;2-n" @default.
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